高錸酸釹
高錸酸釹 | |
---|---|
英文名 | neodymium perrhenate |
識別 | |
CAS號 | 14020-41-8(無水) 18222-80-5(四水) |
SMILES |
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性質 | |
化學式 | Nd(ReO4)3 |
溶解性(水) | 可溶 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
高錸酸釹是一種無機化合物,化學式為Nd(ReO4)3,存在無水物和四水合物[1][2]。它可由過量的氧化釹和240 g/L的高錸酸溶液反應得到。[3]在其溶液中可以觀測到NdReO42+和Nd(ReO4)2+,穩定常數分別為16.5和23.6。[4]
高錸酸釹和NdRe2在高溫下反應,可以製得Nd4Re6O19。[5]
參考文獻
- ^ Varfolomeev, M. B.; Plyushchev, V. E.; Rybakov, K. A. Monoclinic modification of neodymium perrhenate tetrahydrate. Zhurnal Neorganicheskoi Khimii, 1967. 12 (5): 1410-1411. ISSN: 0044-457X.
- ^ Mashonkin, V. P.; Ilyukhin, V. V.; Varfolomeev, M. B. Structure of rhombic rare earth perrhenate tetrahydrates RE(ReO4)3.4H2O (RE = praseodymium-dysprosium). Koordinatsionnaya Khimiya, 1977. 3 (7): 1014-1019. ISSN: 0132-344X.
- ^ Plyushchev, V. E.; Amosov, V. M.; Varfolomeev, M. B. Synthesis and certain properties of lower crystallohydrates of yttrium, lanthanum, and lanthanoid perrhenates. Doklady Akademii Nauk SSSR, 1963. 150 (1): 105-108. ISSN: 0002-3264.
- ^ Petrov, K. I.; Orlin, N. A.; Plyushchev, V. E. Neodymium perrhenate complexes studied by a spectrographic method. Zhurnal Neorganicheskoi Khimii, 1969. 14 (10): 2739-2742. ISSN: 0044-457X.
- ^ Wolfgang Jeitschko, Dieter H Heumannskämper, Marietta S Schriewer-Pöttgen, Ute Ch Rodewald. Preparation, Crystal Structures, and Properties of Rhenates with Multiple Re–Re Bonds: Ln2ReO5 (Ln=Sm, Eu, Gd), Ln3Re2O9 (Ln=Pr, Nd, Sm), and Ln4Re6O19 (Ln=La–Nd). Journal of Solid State Chemistry. 1999-10, 147 (1): 218–228 [2020-08-30]. doi:10.1006/jssc.1999.8237. (原始內容存檔於2018-06-08) (英語).