一锗化钠

一锗化钠
识别
CAS号	12265-93-9
性质
化学式	NaGe
摩尔质量	95.63 g·mol⁻¹
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

一锗化钠是一种无机化合物，化学式为NaGe。它可由氢化钠和锗粉反应制得。^[1]它和氯化亚铜、溴化铵或四氯化锗反应，可以得到金属锗。^[2]^[3]它和锗、四锗化十七锂加热，可以得到红色的Li₃NaGe₂，其中含有[Ge₂]⁴⁻。^[4]

它在电化学领域有所研究。^[5]

参考文献

^ Xuchu Ma, Fengyi Wu, Susan M. Kauzlarich. Alkyl-terminated crystalline Ge nanoparticles prepared from NaGe: Synthesis, functionalization and optical properties. Journal of Solid State Chemistry. 2008-07, 181 (7): 1628–1633 [2022-11-12]. doi:10.1016/j.jssc.2008.06.018. （原始内容存档于2022-06-18）（英语）.
^ Paul F. McMillan, Jan Gryko, Craig Bull, Richard Arledge, Anthony J. Kenyon, Barbara A. Cressey. Amorphous and nanocrystalline luminescent Si and Ge obtained via a solid-state chemical metathesis synthesis route. Journal of Solid State Chemistry. 2005-03, 178 (3): 937–949 [2022-11-12]. doi:10.1016/j.jssc.2004.12.040. （原始内容存档于2022-06-18）（英语）.
^ Boyd R Taylor, Glenn A Fox, Lousia J Hope-Weeks, Robert S Maxwell, Susan M Kauzlarich, Howard W.H Lee. Solution preparation of Ge nanoparticles with chemically tailored surfaces. Materials Science and Engineering: B. 2002-11, 96 (2): 90–93 [2022-11-12]. doi:10.1016/S0921-5107(02)00297-0. （原始内容存档于2018-07-03）（英语）.
^ Lavinia M. Scherf, Antti J. Karttunen, Oliver Pecher, Pieter C. M. M. Magusin, Clare P. Grey, Thomas F. Fässler. [Ge 2 ] 4− Dumbbells with Very Short Ge−Ge Distances in the Zintl Phase Li 3 NaGe 2 : A Solid-State Equivalent to Molecular O 2. Angewandte Chemie International Edition. 2016-01-18, 55 (3): 1075–1079 [2022-11-12]. doi:10.1002/anie.201508044. （原始内容存档于2022-11-12）（英语）.
^ T. Kajita, T. Itoh. Electrochemical performance of highly amorphous GeO x powders synthesized in different alcohols for use in Na- and Li-ion batteries. RSC Advances. 2016, 6 (104): 102109–102115 [2022-11-12]. ISSN 2046-2069. doi:10.1039/C6RA20794D （英语）.

[1] Xuchu Ma, Fengyi Wu, Susan M. Kauzlarich. Alkyl-terminated crystalline Ge nanoparticles prepared from NaGe: Synthesis, functionalization and optical properties. Journal of Solid State Chemistry. 2008-07, 181 (7): 1628–1633 [2022-11-12]. doi:10.1016/j.jssc.2008.06.018. （原始内容存档于2022-06-18）（英语）.

[2] Paul F. McMillan, Jan Gryko, Craig Bull, Richard Arledge, Anthony J. Kenyon, Barbara A. Cressey. Amorphous and nanocrystalline luminescent Si and Ge obtained via a solid-state chemical metathesis synthesis route. Journal of Solid State Chemistry. 2005-03, 178 (3): 937–949 [2022-11-12]. doi:10.1016/j.jssc.2004.12.040. （原始内容存档于2022-06-18）（英语）.

[3] Boyd R Taylor, Glenn A Fox, Lousia J Hope-Weeks, Robert S Maxwell, Susan M Kauzlarich, Howard W.H Lee. Solution preparation of Ge nanoparticles with chemically tailored surfaces. Materials Science and Engineering: B. 2002-11, 96 (2): 90–93 [2022-11-12]. doi:10.1016/S0921-5107(02)00297-0. （原始内容存档于2018-07-03）（英语）.

[4] Lavinia M. Scherf, Antti J. Karttunen, Oliver Pecher, Pieter C. M. M. Magusin, Clare P. Grey, Thomas F. Fässler. [Ge 2 ] 4− Dumbbells with Very Short Ge−Ge Distances in the Zintl Phase Li 3 NaGe 2 : A Solid-State Equivalent to Molecular O 2. Angewandte Chemie International Edition. 2016-01-18, 55 (3): 1075–1079 [2022-11-12]. doi:10.1002/anie.201508044. （原始内容存档于2022-11-12）（英语）.

[5] T. Kajita, T. Itoh. Electrochemical performance of highly amorphous GeO x powders synthesized in different alcohols for use in Na- and Li-ion batteries. RSC Advances. 2016, 6 (104): 102109–102115 [2022-11-12]. ISSN 2046-2069. doi:10.1039/C6RA20794D （英语）.

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